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Volume20, Issue31

August 1, 2024

2470238


Surface Pinning of Mn by Oxidation State Control for the Synthesis of Cobalt-Free, Ni-Rich, Core/Shell Structured Cathode Materials (Small 31/2024)

Calcination of Ni-rich core/Mn-rich shell precursors with a pre-oxidized Mn component demonstrably suppresses Mn interdiffusion. This preservation of the core/shell architecture minimizes surface Ni content, thereby enhancing interfacial stability. Consequently, the core/shell design significantly mitigates surface-induced side reactions and cross-talk effects, leading to reduced growth of interfacial impedance during battery operation. In article number 2400518, Jin Ho Bang and co-workers.



  • JinHa Shim
  • Ye Jin Kim
  • Jin Ho Bang


https://onlinelibrary.wiley.com/doi/10.1002/smll.202470238


Image created by minjeong Kim / Nanosphere