RSC_Energy Environmental Science _ cover Picture
01 December 2020, Issue 12,
Page 4391 to 5200
Highly active and thermally stable single-atom catalysts for high-temperature electrochemical devices
Single-atom catalysts provide unique catalytic properties and maximize the atom utilization efficiency. While utilizing them at elevated temperatures is highly desirable, their operating temperature is usually kept below 300 °C to prevent isolated atoms from agglomerating. Moreover, their applications in high-temperature electrochemical devices have been hindered by the lack of suitable processing techniques for catalyst loading. Herein, we report single-atom Pt/ceria nanocatalysts that are highly active and thermally stable in solid oxide cells (SOCs) operating at 600–800 °C. Our urea-based chemical solution process creates strong Pt–O–Ce interactions that securely anchor isolated Pt atoms to the surface of ceria nanoparticles and suppress their high-temperature migration. These single-atom Pt/ceria nanocatalysts are loaded in the oxide fuel electrode of a SOC via an in situ synthetic process, which reduces the polarization resistance from 28.2 to 0.82 Ohm cm2 at 600 °C. This electrode outperforms the state-of-the-art Ni-based fuel electrode by up to 10 times and delivers extremely high performance in full SOCs in fuel cell and electrolysis modes. Furthermore, it stably operates at 700 °C for over 500 h under realistic operating conditions. Our results provide guidance to resolve the critical issues for the practical use of single-atom catalysts in various industrial processes and accelerate the commercial development of next-generation high-temperature energy devices.
- Jisu Shin
- Young Joo Lee
- Asif Jan
- Sung Min Choi
- Mi Young Park
- Sungjun Choi
- Jun Yeon Hwang
- Seungki Hong
- Seung Gyu Park
- Hye Jung Chang
- Min Kyung Cho
- Jitendra Pal Singh
- Keun Hwa Chae
- Sungeun Yang
- Ho-Il Ji
- Hyoungchul Kim
- Ji-Won Son
- Jong-Ho Lee
- Byung-Kook Kim
- Hae-Weon Lee
- Jongsup Hong
- Yun Jung Lee
- Kyung Joong Yoon
https://pubs.rsc.org/en/journals/journalissues/ee#!issueid=ee013012&type=current&issnprint=1754-5692
Image created by minjeong Kim / Nanosphere
RSC_Energy Environmental Science _ cover Picture
01 December 2020, Issue 12,
Page 4391 to 5200
Highly active and thermally stable single-atom catalysts for high-temperature electrochemical devices
Single-atom catalysts provide unique catalytic properties and maximize the atom utilization efficiency. While utilizing them at elevated temperatures is highly desirable, their operating temperature is usually kept below 300 °C to prevent isolated atoms from agglomerating. Moreover, their applications in high-temperature electrochemical devices have been hindered by the lack of suitable processing techniques for catalyst loading. Herein, we report single-atom Pt/ceria nanocatalysts that are highly active and thermally stable in solid oxide cells (SOCs) operating at 600–800 °C. Our urea-based chemical solution process creates strong Pt–O–Ce interactions that securely anchor isolated Pt atoms to the surface of ceria nanoparticles and suppress their high-temperature migration. These single-atom Pt/ceria nanocatalysts are loaded in the oxide fuel electrode of a SOC via an in situ synthetic process, which reduces the polarization resistance from 28.2 to 0.82 Ohm cm2 at 600 °C. This electrode outperforms the state-of-the-art Ni-based fuel electrode by up to 10 times and delivers extremely high performance in full SOCs in fuel cell and electrolysis modes. Furthermore, it stably operates at 700 °C for over 500 h under realistic operating conditions. Our results provide guidance to resolve the critical issues for the practical use of single-atom catalysts in various industrial processes and accelerate the commercial development of next-generation high-temperature energy devices.
https://pubs.rsc.org/en/journals/journalissues/ee#!issueid=ee013012&type=current&issnprint=1754-5692
Image created by minjeong Kim / Nanosphere