Wiley_ADVANCED MATERIALS
Volume35, Issue18
May 4, 2023
2370125
Atom-Precise Heteroatom Core-Tailoring of Nanoclusters for Enhanced Solar Hydrogen Generation (Adv. Mater. 18/2023)
In article number 2207765, Megalamane Siddaramappa Bootharaju, Jong Suk Yoo, Nanfeng Zheng, Taeghwan Hyeon, and co-workers show how gold doping selectively at the core of a 44-atom silver nanocluster can modulate the electronic structure and enhance the stability of the resulting gold–silver core–shell sub-nanostructure through synergistic effects. Increased interfacial charge transfer due to a favorably modified band alignment makes the core–shell nanocluster a promising cocatalyst for hydrogen generation from solar water splitting.
- Megalamane Siddaramappa Bootharaju
- Chan Woo Lee
- Guocheng Deng
- Hyeseung Kim
- Kangjae Lee
- Sanghwa Lee
- Hogeun Chang
- Seongbeom Lee
- Yung-Eun Sung
- Jong Suk Yoo
- Nanfeng Zheng
- Taeghwan Hyeon
https://onlinelibrary.wiley.com/doi/10.1002/adma.202370125
Image created by minjeong Kim / Nanosphere
Wiley_ADVANCED MATERIALS
Volume35, Issue18
May 4, 2023
2370125
Atom-Precise Heteroatom Core-Tailoring of Nanoclusters for Enhanced Solar Hydrogen Generation (Adv. Mater. 18/2023)
In article number 2207765, Megalamane Siddaramappa Bootharaju, Jong Suk Yoo, Nanfeng Zheng, Taeghwan Hyeon, and co-workers show how gold doping selectively at the core of a 44-atom silver nanocluster can modulate the electronic structure and enhance the stability of the resulting gold–silver core–shell sub-nanostructure through synergistic effects. Increased interfacial charge transfer due to a favorably modified band alignment makes the core–shell nanocluster a promising cocatalyst for hydrogen generation from solar water splitting.
https://onlinelibrary.wiley.com/doi/10.1002/adma.202370125
Image created by minjeong Kim / Nanosphere